Wet-oxidation of acetic acid catalyzed by copper salts.
نویسندگان
چکیده
منابع مشابه
Aerobic Oxidation of Primary Alcohols Catalyzed by Copper Salts and Catalytically Active HydroxylBridged Trinuclear Copper Intermediate
We have developed a new protocol involving the “copper(II) chloride-cesium carbonate” system for the aerobic oxidation of primary alcohols. Cesium carbonates and the solvents such as toluene and 1,2-dichloroethane play important roles to form a catalytically active intermediate containing a m-hydroxyl-bridged trinuclear copper moiety (complex 1). From the X-ray crystal structure of complex 1, a...
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ژورنال
عنوان ژورنال: Journal of The Japan Petroleum Institute
سال: 1982
ISSN: 0582-4664
DOI: 10.1627/jpi1958.25.74